Contact angle measurement characterizes the surface energy of a solid surface.
EAG Laboratories performs optical contact angle measurements and drop shape analysis using a Dataphysics OCA25 instrument. The main application of contact angle measurement is determination of the wetting behavior of a solid surface with a specific liquid. Water drops are used to measure hydrophobicity or hydrophilicity. With individual drops of 2, 3 or more different liquids, the free energy of a surface can be calculated. A common method of surface free energy calculation is the OWRK model, which splits free energy in two contributions: a polar and a dispersive component.
In another application on the same instrument, the surface tension of unknown liquids in air (or in other media) can be measured by analysis of the shape of pendant drops, elongated by gravity.
Ideal Uses of Contact Angle and Drop Shape Measurement
Wetting behavior of coatings
Hydrophobic/hydrophilic properties
Investigate the effect of cleaning and other surface treatments
Surface tension of unknown liquids
Quality assurance and quality control
Strengths
Non-destructive
Quantitative
Surface tension can be measured on (nearly) all surfaces with (nearly) all liquids
Fast and easy: no sample or instrument preparation, no vacuum
Limitations
Minimum measurement area: 1–3 mm diameter for standard droplets, 0.1-0.3 mm for nanodrops
Strongly absorbing materials
Region of interest must be visible in grazing light
Maximum sample size is 20 cm in one direction, no limit in transverse
Minimum sample volume (for measurement of a liquid’s surface tension) is ~1 ml
Contact Angle Technical Specifications
Manual 3-axis positioning
6.5x zoom lens
Camera acquisition for very fast processes
Electronic positioning and dosing of 3 syringes
Nanoliter dosing system to generate very small droplets down to 10 nl
Would you like to learn more about using Contact Angle?
Contact us today for your Contact Angle needs. Please complete the form below to have an EAG expert contact you.
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